Raman Spectroscopy of Conformational Rearrangements at Low Temperatures
Folding and Stretching of Alkanes in Supersonic Jets
This thesis identifies the turning point in chain length, after which alkanes self-solvate into a folded structure instead of an extended stretched conformation. After this turning point, London dispersion forces rearrange isolated n-alkanes into a particular hairpin-structure, while for shorter chain lengths, a simple stretched conformation is energetically preferred. This thesis can locate the experimental turning point for the first time in an interaction-free manner from measurements of unbranched alkanes at low temperatures in supersonic jet expansions. It contains a detailed analysis of the vibrational Raman spectra of the chain molecul…
Mehr
CHF 110.50
Preise inkl. MwSt. und Versandkosten (Portofrei ab CHF 40.00)
Versandkostenfrei
Produktdetails
- ISBN: 978-3-319-08566-1
- EAN: 9783319085661
- Produktnummer: 18258609
- Verlag: Springer-Verlag GmbH
- Sprache: Englisch
- Erscheinungsjahr: 2014
- Seitenangabe: 183 S.
- Plattform: PDF
- Masse: 9'397 KB
- Auflage: 2014
- Abbildungen: 37 schwarz-weiße und 44 farbige Abbildungen, Bibliographie
2 weitere Werke von Nils Olaf Bernd Lüttschwager:
Bewertungen
Anmelden