Development of a New Heterocycle-Forming Reaction and Kinetic Resolution with N-Heterocyclic Carbenes
In this book, the author focuses on exploring new organocatalytic transformations under operationally simple and environmentally friendly reaction conditions. Two new types of catalytic reactions promoted by N-heterocyclic carbenes (NHCs) are described. The oxa- and azacycle-forming reactions of sulfonylalkynols and sulfonylalkynamides are broadly considered to be a new type of activation mode in NHC chemistry, wherein the bond formation with internal O- and N-nucleophiles occurs at the ¿-position of the propargyl sulfones with 1,2-sulfonyl migration. The resulting oxa- and azacycles are core structures in many biologically significant compou…
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Produktdetails
- ISBN: 978-981-1394-00-3
- EAN: 9789811394003
- Produktnummer: 34610693
- Verlag: Springer Singapore
- Sprache: Englisch
- Erscheinungsjahr: 2020
- Seitenangabe: 124 S.
- Masse: H23.5 cm x B15.5 cm x D0.7 cm 201 g
- Auflage: 1st ed. 2019
- Abbildungen: Paperback
- Gewicht: 201
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